In Diamond and Pearl breed male Medicham with Thunderpunch with a female Infernape. If you got a male Infernape breed Ditto with male Infernape until you get a female Chimchar and then follow the steps again. In Platinum go to the move tutor on Route 212 and teach Thunderpunch. It will cost you 6 blue shards and 2 red shards. Shards can be found in the Underground. In HeartGold and SoulSilver go to the Battle Frontier you will find a house with three men one of them will offer to teach Thunderpunch. It will cost you 64 Battle Points. Finally you have your Infernape with Thunderpunch. I hoped I helped you.
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You need to get it from a tutor or as an egg move.
Yes, you need to use the Move Tutor.
Magmar learns thunderpunch by egg move.
I think this is a good move set. I'm trying to teach this to my Infernape. Flamethrower Thunderpunch Earthquake Brick Break I think Infernape's a physical attacker so I don't know if Flamethrower will be any good. Firepunch would be a good substitute for Flamethrower though since it's a physical move.
At the Battle Fronitier a house with 2 old ladies. One of them should teach you thunderpunch for the right amount of Battle Points.