Pokemon Emerald was only released as a GBA cartridge, the DSi XL has no GBA slot so you can't play it.
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Yes, the Nintendo DS and Nintendo DSi can link together to play Pokemon. Keep in mind that games such as Pokemon Diamond and HeartGold cannot link with Pokemon Black (2) and White (2) for battling and trading.
Yes, as long as the Pokemon game is a DS Pokemon game. Since the DSi does not have slot 2, it cannot play GBA Pokemon games Therefore the DSi can play: - Pokemon Diamond, Pearl and Platinum - Pokemon Black, Black 2, White, and White 2
No, Pokemon Black and White are compatible with all versions of Nintendo's DS line.
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