it is hard, but as soon as your person touches the big ball, press A as quick as possible. NOTE- this is really hard if you are doing the level with a swinging spike ball above you.
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big balls
i think 5
I think there is only one masterball in that game but ask someone more experient. The one i know is at Saffron in the big building after you beat the Team rocket leader you get it from the owner of that building
For Fire Red, I believe you could get 1 net ball in the game. One of them is from the fisherman south of Lavender City, and if you catch a magikarp and give it to him and it is big enough, he will give you a net ball.
Find the line of symmetry