go to lillycove and there is a giant red building. Go inside and there are small square machines. And there are people around them. Talk to them.
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There are no PokeBlocks in HG/SS.
If you put Soothe Bell on a Pokemon or give it Pokeblocks.
Pokemon can only have a set number of pokeblocks. Once they have eaten that set number, they will never be able to eat any more. The only way that you can get your pokemon all the way to the highest amount of a skill is to make really good pokeblocks.
No.
Depends on it's nature allthough usually it likes blue pokeblocks or pokeblocks with dry qualities.