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First beat the elite four, then a new place called N's Castle will appear.

N will show up and talk to you. After that, Zekrom will appear and you MUST catch him to move on. If you defeat him you have to try again. I used a quick ball and caught him in one shot. You don't have to use your Master Ball. I would suggest saving that for Thundurus.

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Q: How do you get zerkom in Pokemon White?
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