You have to trade with silver to get, or blue and yellow.
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near safari zone were the grass is
vulpix is not in Pokemon platinum version.
You can't catch vulpix in Heart Gold, though you can catch it in Soul Silver. On the small route 37, Below Ecruteak City, you can find: ~Heart Gold = growlithe ~Soul Silver = vulpix (they both evolve using a fire stone)
In Gold, you can only get it through trade. But for Sliver players, you can find it in Routes 7, 8, 36, and 37.
You can't find a Vulpix in Pokemon FireRed version. That pokemon is version-exclusive to Pokemon LeafGreen.