In castelia city go near Pokemon center and along path u see signs. Read these to find prime pier
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castelia cty
I have a feeling it is the boat u ride to the p2 lab for the genesect event.
no, go to castelia city and then go to liberty pier the captain there will take you to liberty island and victini
talk to the person on the first pier of castelia city to get the one that your starter is super effective against. for the others, go to pinwheel forest
in castellia city, just got to every pear till you see the gym leader burgh