you have to surf from olivine city
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Cianwood City
The Pharmacy is in Cianwood City.
In the cliff cave in cianwood city
It is on Cianwood City Island. You have to surf there from Olivine City. (NOTE: the gym in Olivine is actually the 6th Gym battle so go to Cianwood Gym first) Before you go to Cianwood City make sure you visit the Olivine lighthouse top floor to talk to the Olivine Gym Leader about a sick Pokemon first.
in the caves