You can't use poffins in this game
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first go to hearthome city and go to the Pokemon fan club talk to the chairman and he will give you a poffin case =p
Where You Get The Poffin Case:-Original Answer- Enter the Pokemon Fan Club located next to the Poke Mart. Talk to the FanClub chairman and he'll give you the POFFIN CASE-Improved Answer-First, go to the Pokemon Fan Club. It is located in Hearthome City. There's a man standing in the club who is obviously the owner, due to his brown suit, brown hat, and white beard/hair. He is behind the big table, standing there facing the door. If you talk to him, he will give the Key Item, the Poffin Case, to you.The Poffin Case is for making Poffins, which can improve a Pokemon's performance in Shows.
In the Pokemon Fan Club, in Hearthome City.
The Poffin maker's house, it is left from the Pokemart in Hearthome City and ask the lady in front of the Poffin Maker. If you need a poffin case go to the Pokemon Fan Club and talk to the old man at the couch.
Go to Hearthome City, find the house that has a heart on top of the door. ( Also called Pokemon Fan Center) SIGGYh83r Talk to the chairman inside (sitting on the couch) and he will give you a poffin case.