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You get it in The Team Aqua Hideout by Lilycove City.
team aqua hideout at lilycove city
you get it in team aqua/magma's hideout in lilycove
the master ball is in team aquas hideout. When u find the room with 4 pokeballs the one on the top left (I think) is the master ball.
You can find one in the Aqua hideout or by winning a lottery.