u can't get it it is not a tm
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The only way Alakazam can learn Fire Punch is through a Move Tutor on Pokemon Emerald Version.
You can only "learn" Fire Punch in Diamond via breeding a Pokemon with another who already knows Fire Punch (Magmar for example)
Fire Punch is not an TM or HM in Pokemon FireRed. It is learned by level up or by breeding for Pokemon that can learn it.
Prob Go To The Island Where You Can Have To Pokemon In The Day Care; Not The One Where You Can Only Have One - - - Below Cereun City. Put In A Hitmonchan That Knows Ice Punch & A Gengar. You Should Have A Gastly With The EGG-MOVE Ice Punch.
Hitmonlee is more defencive and Hitmonchan is high in attack. Hitmonchan also learns and the punches: ice punch, fire punch, and thunder punch