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To go to route 222, you must have beaten CANDICE (7th gym of sinnoh) and battle or catch DIALGA (ruler of time).

Then go/fly to PASTORIA CITY, leave the city by taking the route 213. Finally when you reach the HOTELS(near valor lakefront), go through route 222 (the man will not block the passage now).

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Q: How do you get route 222 on Pokemon diamond?
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