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Exclusively found in Area 2 of the Safari Zone. Note that Houndoom is not available in Ruby or Sapphire - only Emerald.
Houndour evolves at level 24 into Houndoom.
Unfortunatley, you can't catch Houndoom on Ruby. You need to trade it from Emerald. On Emerald, you can find Houndour in the Safari Zone Extention (after you beat the Elite Four go to the place where the two guys where blocking the path).However,it is a rare pokemon, and you need to be patient. Houndoom must evolve from Houndour because Houndoom can't be found in the wild.
Houndoom cannot be found in Pokémon Ruby or Sapphire; you must trade to obtain it. Houndour, which evolves into Houndoom, can be found in Pokémon Emerald, in the new section of the Safari Zone which opens after you beat the Elite Four. You can also find Houndour in Pokémon XD or Houndoom in Pokémon Colosseum and trade them to Ruby.
houndoom learns flamethrower at level 50.