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You get it at Ambrette Town in the laboratory. And it's not an HM; it's TM94. Rock Smash went from being an HM to a TM in the 5th generation games (Black/White/Black 2/White 2).
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This HM is located at the Parfum Palace. More specifically at the center of the southwestern hedge maze.
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Use wonder mail code: 1?1? 7?Y? 4??6 6F?6 F4N6 MC??
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