One way to getting a Water Stone is to talk to a guy in Castelia City and answer with Panpour and he will give you a Water Stone and other ways of receiving Water Stones in Pokemon White is by encountering dust clouds in the various caves such as Wellspring Cave, Chargestone Cave, Victory Road and Mistralton Cave.
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Exchange Blue Shard with the Waterstone. You'll find waterstone in Abandoned Ship, too.
Its evolve to Vaporeon from eevee
You can get one in Solaceon Ruins with the dowsing machine app on the poketech.
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You can get waterstone in route 25 at Bills cottage you will see Bills grandfather ( Likitounge (everstone)oddish(leafstone)staryu(waterstone)growlithe(firestone)pichu(thunderstone)