Electivire is a 4th generation Pokemon meaning it was created after the GBA Pokemon games so that means its not obtainable in any GBA game including emerald.
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Electivire cannot learn Ice Punch via Level-Up. The only way to get an Electivire with Ice Punch is to breed (with Hitmonchan or Medicham) and then evolve the hatched Elekid into an Electabuzz, then Electivire.
No, you can't get any electivire in fire red even you use thunder stone on Electabuzz
electivire
Froslass is from the ice gym, electivire is from electric gym, tangrowth and dusknoir are from trainers
you cant