you can only aquire one from the game corner as a prize and you can get one in the safari zone if you are very luck you will see one in the first patch of grass you see when you first walk in the safari zone
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you can not catch scyther in Pokemon ruby,emerald or sapphire . you have to trade them from Pokemon fire red or leaf green.
Trade It From Pokemon Fire Red Or Leaf Green
The Pokemon 123 in leaf green is scyther, i think you can get it by trading it from fire red...
Chansey, Scyther, Tauros, Kangaskhan and Dragonair.
You can do it by BREEDING - Scyther female and BUG male with silver wind attack... in fire red that may be hard...