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This is the code for "Catch Trainers Pokemon" B6C5368A 08BE8FF4 B8D95CFE 06ED6EA1 E151C402 8A229A83 8E883EFF 92E9660D Press L+R in battle to be able to catch trainers pokemons as if they were wild.
You can't steal Pokemon however in Pokemon colosseum and Pokemon xd gale of darkness you can snag shadow Pokemon from trainers.
Yes, You can catch Groudon in Pokemon Emerald.
You can't catch one in Pokemon Emerald.
No you cannot catch Entei in Pokemon Emerald.