In Pokemon platinum larvitar can be found in the north area of route 210 after obtaining the national pokedex, you have to use the poke radar to find one
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No you cannot catch Larvitar in Pokémon Emerald.
Not naturally, no.
find a caterpie in eterna forest then level it to level 7 and it will evolve into larvitar
Larvitar evolves into Pupitar at level 30, then finally into Tyranitar at level 55.
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