To obtain Electivire you must trade Electabuzz holding a Electirizer.
You can catch Electabuzz at Route 10 (Kanto) at any time of day and at the Johto Safari Zone in the forest section at any time of day.
The Electirizer can be obtained in Cerulean Cave (Kanto) by using Rock Climb in the north-east corner of B1F
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Electivire cannot learn Volt Tackle in Pokemon HeartGold. Only pichu, pikachu, and raichu can learn volt tackle.
you cant,but you can get a electabuzz,and trade it with it holding a item called....................er,i forgot.but its a electric item.
You can't catch Skitty in Pokémon HeartGold or Pokémon SoulSilver but you can catch it in the Hoenn Field in the PokéWalker device and then transfer it over into HeartGold or SoulSilver.poke walker .
You trade for it.
Unfortunatly, not -.-