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To obtain Electivire you must trade Electabuzz holding a Electirizer.

You can catch Electabuzz at Route 10 (Kanto) at any time of day and at the Johto Safari Zone in the forest section at any time of day.

The Electirizer can be obtained in Cerulean Cave (Kanto) by using Rock Climb in the north-east corner of B1F

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Q: How do you catch electivire in heartgold?
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