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So far, the only way to get Deoxys in Pokemon Platnum (or in any Pokemon game for that matter) has been through Nintendo events.
You can catch them on the route where you catch the Kadabra...
A Pokemon's catch rate can range from 3 (hardest to catch) to 255 (easiest to catch). Hardest to catch (catch rate = 3): - Uxie - Mesprit - Azelf - Heatran - Regigigas - Giratina - Cresselia - Manaphy - Darkrai - Arceus Easier to catch (catch rate = 30): - Dialga (& Palkia) Easiest Sinnoh legendary to catch (catch rate = 45): - Shaymin
You can not catch butterflies, if you are seeking to catch a beautifly, they are not wild. You have to catch a silcoon in Eterna Forest then evolve it into Beautifly
You can onl catch LUNATONE in SAPPHIRE but you can catch solrock in emerald