first you need to catch ditto on route 218 (the very first grass patch from canalave city) then breed at the day care.
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breed a ditto with a piplup, a prinplup, or an empoleon. or breed 2 piplup, prinplup, or empoleon.
You can only breed either prinplup or empoleon if you want another piplup and breed it with ditto to get the piplup.
No
Yes you can. They are both part of the ground egg group. But you can breed any Pokemon (excluding legendaries) with ditto
It will not learn it on its own. Just buy the TM or breed/tutor it.