Usually if you plug the usb cable (controller charger cable) into the ps3 console and the ps3 wireless controller it will sync the controller with the console. I had this problem when I went to a friends house and brought my extra controllers. The Controllers just set there and blinked till I plugged it into his usb cable that hooked up to his ps3 console.
Hope this helps
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You have to have the wire that connects the controller conected to the PS3 and then you hold the middle button
About £20
With tools obviously!
It is wireless and not connected.
Your controller should come without any charge, after you have charged the controller it will be connected to the PS3. If you had it with charge for some reason, just connect it to your PS3 with the USB cable.