You have to have the wire that connects the controller conected to the PS3 and then you hold the middle button
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I believe that the PS3 has wireless capability for controllers. If you don't have a PS3 wireless controller, then buy one at any electronics store. The wired controllers have a USB connection at the end of it.
With tools obviously!
About £20
It is wireless and not connected.
Usually if you plug the usb cable (controller charger cable) into the ps3 console and the ps3 wireless controller it will sync the controller with the console. I had this problem when I went to a friends house and brought my extra controllers. The Controllers just set there and blinked till I plugged it into his usb cable that hooked up to his ps3 console. Hope this helps