Your controller should come without any charge, after you have charged the controller it will be connected to the PS3. If you had it with charge for some reason, just connect it to your PS3 with the USB cable.
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Guitar Hero for the PS3 comes with 80 different songs. It is possible to add your own songs onto your PS3 by going to music studio and then to recording studio.
no
You can't mod the PS3 version, so you can't add Herobrine in.
There are procedures that are described in the PS3 when you try to add friends and involve sending a message to someone
1.go to freinds,add freind.....2.UR DONE