Train it as you train all pokemon.
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It's pretty obvious... EV train (I suggest EV Training in Defense)...
train them without using rare candy's
yes.. you can
probly at the pokemon leuge
No,to EV train you need to win experience points,try breeding your lv 100 Pokemon and EV train him. I thought it would be informative to add that you can give the level 100 Pokemon 10 of each vitamin in five stats and 1 vitamin on the sixth stat. Sorry but that's the best you can do.