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No,to EV train you need to win experience points,try breeding your lv 100 Pokemon and EV train him.
I thought it would be informative to add that you can give the level 100 Pokemon 10 of each vitamin in five stats and 1 vitamin on the sixth stat. Sorry but that's the best you can do.
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Earn +20 ptsQ: Can you EV train at level 100?
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How can you win 100 battles in the battle tower?
You need to EV train your pokémon and use good movesets.
How do you EV train a legendary Pokemon?
Train it as you train all pokemon.
What is the best way to train Pokemon on Heartgold?
It's pretty obvious... EV train (I suggest EV Training in Defense)...
How do your pokemom to level 100?
just train
Is it better to ev train when you are a high lv?
If you mean a high level like 30+ then yes but if 65+ i dont think it would be necessary.
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