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No,to EV train you need to win experience points,try breeding your lv 100 Pokemon and EV train him.

I thought it would be informative to add that you can give the level 100 Pokemon 10 of each vitamin in five stats and 1 vitamin on the sixth stat. Sorry but that's the best you can do.

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13y ago

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Q: Can you EV train at level 100?
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