The highest base DEF is 5000.
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'Shield and Sword', a Normal Spell Card, can do that.
Battle Footballer, Soul Tiger and Renge - Gatekeeper of Dark World, all with 2100 DEF.
Not necessarily, as there are a few genuine monsters with 5000 ATK and DEF, namely Dragon Master Knight, Malefic Truth Dragon and Five-Headed Dragon.
The best card in yugioh is the judegement dragon card.
Blissey