In Dragon Ball Z, Krillin doesn't ever die 'for good', but he does die a few times.
First time, being in Dragon Ball. Second time, being on Namek.
He may be dead at the end of GT, but it's not comfirmed.
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yes frieza kills him
Krillin has died four times.
goku met krillin in the original dragon ball series where they went to train under master roshi krillin hated goku, but after a while they became best friends and in case u are wondering his best friend is krillin.
frieza killed krillin on planet namek when goku tried to hit him with the spirit bomb but failed also when krillin was killed goku turned super saiyan for the first time
Episode 95: Transformed at Last. After being hit by the spirit bomb and taking a short leave of absence, Frieza returns and levitates Krillin, then explodes him. This happens near the end of the episode (around 19 minutes into my 24:11 file)