There are game bundles that come with a controller or vice verse. Both are also sold separately
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Yes when your controller needs to be charged you can use the charging cable and still use the controller to play the game. Always make sure your system settings automatically turn off your controller when you turn off the PS3. Remember the PS3 will not charge the controller when it is off.
It's a PC controller and you need a PS3 controller. It's a PS3 and the accessories are not interchangeable any more than the games are. Get the PS3 move bundle that comes with a game and both a Move and a navigational controller as well as the Playstation Eye camera.
leave the PS3 turned on and change the settings to turn off the controller when the PS3 is turned off. You can turn the controller and the PS3 back on by pressing the PS3 emblem on the controller
Your controller should come without any charge, after you have charged the controller it will be connected to the PS3. If you had it with charge for some reason, just connect it to your PS3 with the USB cable.
Yes, the USB PS2 to PS3 Controller Converter Adapter Cable can be purchased in white.