yeah however you won't find Entei if you didn't start with Bulbasaur.
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Choose Squirtle as your starter. Beat the elite four. It will become wild. Then you have to search for it. You have to choose bulbasaur as your starter
I do not know where he is after beating elite four soul silver. I hope to find him soon.
No you can't use the azure flute after you beat the elite four
You wait until you beat the elite four and professor Elm will give it to you when you beat the elite four.
You find Heatran in the third room at the end of Stark Mountain, which is available after you beat the Elite Four.