no, it'll only learn at level 14, just when it evolves.
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At level 14 when it evoleves into monferno ________________________ I believe this is incorrect. I have a level 32 Monferno and it still hasn't learned mach punch. I believe it learns it when Monferno evolves into Infernape, but this is just a guess.
Chimchar Evolves into Monferno @ lvl. 14 but when it gets to level 14 let it evolve or it wont learn mach punch.
Level 1- Scratch, Leer, Ember Level 7- Ember (Again.) Level 14- Mach Punch Level 16- Fury Swipes Level 19- Flame Wheel Level 26- Feint Level 29- Torment Level 36- Close Combat Level 39- Fire Spin Level 46- Slack Off Level 49- Flare Blitz
Level it up until it evolves into a Monferno, then level it until it learns double kick, double kick is super effective against all the gym leaders Pokemon. that bull crap here how it goes that monferno don't learn double kick it will learn mach punch which isn't very strong but very much fast it will evolve at lv14 guys shut up it learns both double kick and mach punch so i will settle this when your chimchar evolves it will lern mach punch later on in the evolstion it will learn double kick SORTED There is a much simpler way. Just catch a Machop train it to level 7 or 8 and beat all the gym trainers.
Like many pokemon that are evolved with stones, poliwrath learns very few moves. The few that it does are dynamic punch (level 32), mind reader (level 43), and circle throw (level 53).