yes but it has to be on a certain level i think level 31 34 36 38 sometin like that
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Leafeon learns leaf blade at level 71.
To evolve your Evee into Leafeon, get a leaf stone, and use it on Evee, and it will evolve into Leafeon! Have fun with Leafeon! -Garrett
The attacks Leafeon can learn via level up and through the use of TMs in Pokémon Platinum include Tackle, Quick Attack, Razor Leaf, Magical Leaf, Last Resort, Leaf Blade, Bullet Seed, Hyper Beam, Return, Frustration, Solarbeam, Iron Tail, Shadow Ball, Dig, Aerial Ace and Energy Ball.
level 36
there is no TM at all that contains leaf blade