Yes. Go to lilycove dept storeTalk to the lady at the rightShe will give you a loto number, if you are lucky enough to get all the numbers similar to your Pokemon id, you will win a Master Ball !
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In Lilycove you can play contests shop at the department store and win an exp share, a type of stone or a master ball. The first time there you battle your rival.
There is no correct answer for lottery. If you use a real GBA console, come back every day and if numbers match your trainer ID number, then you will win a master ball.
You get it in The Team Aqua Hideout by Lilycove City.
You get the Master Ball in the Aqua base off of Lilycove. It is in an area with two Electrodes and one Gold Nugget.
team aqua hideout at lilycove city