No. They can't. Alakazam is in the Human-like egg group, while Gardevoir is in the Amorphous egg group. Thus, due to having different egg groups, they cannot breed.
However, Alakazam can breed with Machamp, Cacturne and even Lopunny! Also, Gardevoir can breed with ghosts like Gengar and even Muk, a pile of sludge! Yuck!
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Pokemon in the same egg-group as gardevoir
No im afriad not, to breed the two Pokemon must be of the same type and different genders
In my opinion, either Alakazam or Gardevoir because they both are found in the beginning (although Ralts learns confusion fast, where as Abra doesn't learn a move until level 16 when it evolves into Kadabra) and have high special attack stats. Also if you play emerald alone and don't have anyone to trade with then definitely get Gardevoir because to get Alakazam you have to trade Kadabra which sometimes is hard to do/can't do until later in the game. This is just my opinion.
you cant get gardevoir but you can catch either ralts or kirlia and evolve it int gardevoir(ralts to kirlia to gardevoir to gallade
Here is a list of all the Psychic type pokemon. Abra Kadabra Alakazam ralts kirlia gardevoir Lunatone Solrock Mr.Mime Mime.jr bronzor bronzong espeon Chimecho chingiling