It is difficult to objectively say what the best fire Pokémon in Emerald version is. Arguably it is Camerupt in competitive play.
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you can't get him on emerald ruby or Sapphire. you have to trade him from Pokemon leaf green or fire red to emerald. on Pokemon fire red and leaf green you get him at the end of island 1.
The best fire type Pokemon in Emerald Version is likely Camerupt(evolves from numel).Camerupt has very high defense and attack stats,at the cost of its speed. It can learn many powerful moves such as Earthquake,Flamethrower,Fire Blast,Overheart,Lava Plume,etc.
The only way to get Hoppip on Pokemon Emerald is to trade from Fire Red or Leaf Green.
Sorry, but the only way to obtain Eevee in Pokemon emerald, is to trade from Pokemon Fire read, or Leaf green. ;)
you can trade with Pokemon leaf green and Pokemon fire red