The best Pokemon to catch in emerald is rayquaza. It has great speed and awesome strength. If you teach it the right it might the strongest Pokemon.
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No you cannot catch Celebi in Pokemon Emerald.
No I don't believe you can catch a ledyba in emerald
You can onl catch LUNATONE in SAPPHIRE but you can catch solrock in emerald
yes you can catch a Manaphy on emerald. (if you have a game shark)
Yes, You can catch Groudon in Pokemon Emerald.