Wolverine, he's the best there is at what he does
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Grizzly bear, by far.
Captain America! Black Widow might be agile and quick, but Captain America is super strong and has that unbreakable shield.
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The wolverine would assuredly try and avoid the fight by all means necessary, but if the fight ensued, the wolverine would certainly be overpowered by the much stronger and larger tiger.
It would come down to Hulk, superman, and thor. Superman and Thor would work together to fight hulk. And then superman vs thor. With all power from superman, he can pick up thor's hammer and throw it at Thor. So superman would win