episode 90 called "A Shinobi's Determination"
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Neji and Hinata do not fight in Shippuden. Shippuden is the second part of Naruto after a 3 year time jump. I think it's episode 46-47 of Naruto (without the Shippuden). Since the time jump they have been getting along a lot better and it's been revealed that they fight together now as "comrades" according to Hinata's father, Hiashi. Also, there are hints of an unrequited affection from Neji towards Hinata. Hinata, of course, still love Naruto. However, it's clear to see that Neji is no longer harboring hatred for Hinata. Therefore, NO MORE FIGHTS! They do train together though.
naruto shippuuden episode 311
yes maam or sir he does
When he fights Deidara shippuden 32 I believe
for the second time it could possibly be naruto shippuden episode 217 as manga 475 is naruto shippuden episode 208 and in manga it is only 9 more chapters left until they meet again so it could be somewhere between naruto shippuden 215 and 219