Naruto Shippuuden Episode 1, Possibly 2, If i am correct, when you download the episode, Episode 1 and 2 are stuck together.
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Answerin episode - 33
It's episode 33.
No where. Naruto and Sakura never kiss.
He masters it in Naruto Episode 53- Long Time No See: Jiraya Returns!
naruto shippuuden episode 311