Yes. Alec changed before Jane because he was elder to her and Jane was too young to be changed into a vampire before Alec.
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no and the Volutori are not a family its just a bunch of royal vampires with special talents
The Volturi had their eyes on Alec and Jane (biological siblings). It was suspected that they were doing witchcraft, so they were going to be burned at the stake. That's when Aro stepped in. He turned them both into vampires and welcomed them into the Volturi clan. Also I'm assuming that they were changed into vampires sometimes far in the past (ranging from 1400's to 1700's seeing as they were going to be burned at the stake).
Alec is a member of the volturi, a "royal" vampire clan. His gift is to cut of all senses, rendering his victim helpless, and his twin sister is Jane. He and is sister are said to be over 3 thousand years old.
There are acutually five characters from the Volturi. They are: 1. Alec 2.Marcus 3.Aro 4.Caius 5.Jane
Aro-Michael Sheen Caius-Jamie Campell-Bower Marcus-Christopher Heyerdahl Jane-Dakota Fanning Alec-Cameron Bright Demetri-Charlie Bewley Felix-Daniel Cudmore Heidi-Noot Seear