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The Volturi had their eyes on Alec and Jane (biological siblings). It was suspected that they were doing witchcraft, so they were going to be burned at the stake. That's when Aro stepped in. He turned them both into vampires and welcomed them into the Volturi clan. Also I'm assuming that they were changed into vampires sometimes far in the past (ranging from 1400's to 1700's seeing as they were going to be burned at the stake).

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Q: When did alec in new moon become a vampire and why?
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