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I'm not sure of when Naruto fights Tobi alone, but there is an episode in Shippuden in which he fights Tobi with a group of six or so shinobi whilst on a quest for Sasuke. This episode is number 134, called "Banquet Invitation".

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15y ago

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Q: Naruto what episode did Naruto fight with Tobi leader ogf the akatsuki?
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