I think its when Sakura,Naruto and Sasuke were fighting Orochimaru. And in some frustated moment, Orochimaru quickly bites Sasukes that gave him the CURSE MARK aka MANGEKYO SHARINGAN. They didn't make the episode yet but he gets it and kills Itachi before Itachi pulls out his eyes, but first Itachi transfers all his jutsus he know then drops dead.
At the end of episode 141, it shows Sasuke looking that the sun with his mangekyou sharingan.
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Kakashi unlocked the Mangekyo Sharingan barely months after he obtained his Sharingan from Obito. Since it was only just revealed in the manga, it will be a long time until the actual episode is released. Kakashi has been shown using Mangekyo Sharingan powers as an adult, but obtained it while still young.
Kakashi Hatake receives his sharingan way before the episodes came out. He received his sharingan after Obito Uchiha sacrificed his life to protect Kakashi and Rin. Kakashi obtained his Mangekyo sharingan after killing Rin.
Kakashi is first seen with the Sharingan is episode 8 in Part One of the series. But in factuality(word I made up) he obtains it in episode 3 during Kakashi Gaiden (Kakashi Chronicles).
there is a 2 part flashback on episode 119-120 which tells you the story of him getting the sharingan
This has only just been revealed in manga issues 604 and 605, so it will be a long time before it appears in an episode.
Its Mangekyo sharingan! The final stage of the Sharingan is the Eternal Mangekyou Sharingan, the difference between the normal Mangekyou and the Eternal Mangekyou is: that each time you use the normal Mangekyou your eyesight gets worse and worse and you eventually become blind. With the Eternal Mangekyou your eyesight will never fade. yes i know this but I've herd the final stage of the sharingan is obtained by sasuke and it is blue
Itachi did not lie to Sasuke when he informed him that your friend has to die for you to get Mongekyo Sharingan, but you do not have to kill your friend. All your friend has to do is die, or a carrier of Mongekyo can give it to someone. That is how Sasuke got his new power, from Itachi giving it to him.
Sage mode increases speed and strength and Sauske's mangekyou sharingan is used for ninjutsu and genjutsu. So I would go with Naruto.
Sasuke is shown using his eternal mangekyou sharingaan in manga chapter #574. In this chapter he uses his new Susanoo to obliterate a small platoon of white zetsu within seconds. It is also described he was now able to see the darkness in souls of his enemy.
No only the Byakugan