Season Six | McStroke
He also had a mustache / beard in Season Four | Brian Wallows & Peter's Swallows
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Peter wasn't in college, but the episode was Season 2|Episode 10 Running Mates
125
When he fights Deidara shippuden 32 I believe
Justin Bieber does not have the Peter Pan syndrome is a disorder in which a man is unable to grow into maturity. Justin Bieber just has good genes which is why he looks youthful.
The first episode of Shippuuden or 221 if you do a total count.