Naruto and Mizuki's fight isn't until the shippuuden(hurricane) series. mizuki threatens to kill sakura for revenge if naruto doesnt come to fight him. finally, in episode 101 of shippuuden, naruto comes and confronts mizuki after 2 episodes of him threatening naruto. naruto then prepares his rasengan and defeats miziki by him dodging the first rasengan, and is really a shadow clone, and uses a rasengan right into the top of mizuki's head.
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The episodes featuring Naruto versus Mizuki are shown in the Mizuki Strikes Back Arc which is five episodes. Naruto versus Mizuki are shown in episodes 142-147.
Yes in a filler episode were Mizuki escapes from prison with two accomplice's
Your question isn't direct enough. What season of Naruto? (The Original or Shippuden?) and return to where? He shows up multiple times.
Madara's debut appearance as Tobi is Naruto Shippuden Episode 32: Return of the Kazekage.
First time they are seen thogheter is in episode 32
The last naruto episode (not shippuden) is Naruto Episode 220