First time they are seen thogheter is in episode 32
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Sasuke sees Tobi when he fights Deidara. Tobi flees after Deidara self-detonates. However, after he kills Itachi, Sasuke meets Tobi, who reveals himself as Madara Uchiha. The Shipuden Episode is 139.
the first episode of season 4
He is first seen in chapter 35/episode 20.
She doesn't! He is way to cute for her!!! Sakura loves Sasuke in a few ways but has feelings for Naruto. In manga she kills him anyway.
*Akitoki Hojo Episode 137 While episode 137 is his first appearance in the series, they meet him in the 2nd movie Castle beyond the Looking Glass before the events in 137.