Yes in a filler episode were Mizuki escapes from prison with two accomplice's
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Naruto and Mizuki's fight isn't until the shippuuden(hurricane) series. mizuki threatens to kill sakura for revenge if naruto doesnt come to fight him. finally, in episode 101 of shippuuden, naruto comes and confronts mizuki after 2 episodes of him threatening naruto. naruto then prepares his rasengan and defeats miziki by him dodging the first rasengan, and is really a shadow clone, and uses a rasengan right into the top of mizuki's head.
you have to beat them in master road
yes in original Naruto in the {Chunin exams [I think]}
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Heaven Knows - Nana Mizuki song - was created on 2001-04-25.