gaara was 8 years old
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when Sasuke attacks the five kages then during their meeting A 4th raikage fights Sasuke then Gaara with Temari and Kankru will aid .. so Gaara confronts Sasuke with his Sand Shield protecting all from his Amatersu. the chapter 462to464 anime 203
after the chunin exam To be a little more specific, Naruto encounters Gaara episode 77 Light vs. Dark: The Two Faces of Garra. They don't start fighting until, 78-80, naruto's Ninja Handbook.
If this question contains the scene where Gaara comes in during Sasuke's training at the mountains, then the episode you're looking for is episode 63. The scene also appears in episode 75.
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No.