Whoa... let's give this a shot. *deep breath*
Episode 21 (First appearance)
Episode 34 (Forest of Death)
Episode 48-50 (Gaara vs Rock Lee)
Episode 58 (Hospital)
Episode 65-67 (Gaara vs Sasuke)
Episode 74-75 (Gaara vs Sasuke cont.)
Episode 76 (Gaara's past revealed)
Episode 77-79 (Gaara vs Naruto)
Episode 125-127 (Gaara and Rock Lee vs Kimimaru)
Episode 216-220 (Ultimate Weapons Arc)
And entering Shippuden...
Episode 4-32 (Kazekage Retrieval Arc)
Episode 182 ("Gaara's Bonds")
A critter who steals Gaara's form appears in Episode 186
And then Episode 198 onward in the Gokage Summit Arc, up through current episodes!!
He also graces us with his presence in Naruto the Movie 2 Stone of Gelel and Naruto Shippuden the Movie 3 Inheritors of the Will of Fire
Hope this helps! I pray I didn't miss anything!
=^^=
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